Front dynamics during diffusion-limited corrosion of ramified electrodeposits
Article Abstract:
The diffusion-limited corrosion of porous copper clusters in thin gap cells containing cupric chloride were subjected to experimentation. The process was well-described by one-dimensional mean-field model for the generic reaction A + B(static)->C(inert) with only one diffusing reactant and one static reactant reacting to produce an inert product. This was obtained by careful comparison of corrosion front velocities and concentration profiles from phase-shift interferometry with theoretical predictions.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
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Assessing induced folding of an intrinsically disordered protein by site-directed spin-labeling electron paramagnetic resonance spectroscopy
Article Abstract:
The induced folding of the intrinsically disordered C-terminal domain of measles virus nucleoprotein is studied using site-directed spin-labeling electron paramagnetic resonance (EPR) spectroscopy. The results highlight the suitability of site-directed spin-labeling EPR spectroscopy to identify protein regions involved in binding and folding events, while providing insights at the residue level.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Effects of slow substrate binding and release in redox enzymes: Theory and application to periplasmic nitrate reductase
Article Abstract:
The thermodynamics and kinetics of substrate binding which affects the position and shape of a catalytic voltammogram in the most general case where substrate could bind to and be released from any redox state of the active site is demonstrated.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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