Aqueous solvation dynamics at metal oxide surfaces
Article Abstract:
Time resolved investigation of aqueous solvation is performed, to compare the behavior of bulk water, with water in the proximity of metal oxide surfaces. Results suggest that interfacial water is restricted to a thickness of less than 5 angstrom and the high-frequency collective dynamics of water does not seem to be affected by the interface.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Association and dissociation of an aqueous amphiphile at elevated temperatures
Article Abstract:
The temperature-dependent study of the aggregation and subsequent disaggregation in water of tert-butanol is presented. The results are relevant to the dependence of protein stability and micelle formation on temperature, as both proteins and micelle structures are built from amphiphilic rather than nonpolar subunits.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Theoretical study of the 1,3-hydrogen shift of triazene in water
Article Abstract:
The 1,3-hydrogen shift of triazene in aqueous solution is studied with a combination of QM/MM methods. It is concluded that the participation of water molecule in the proton-shifting process significantly decreases the activation energy and the overall effect of the solvent is somewhat lower, but still important.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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- Abstracts: Thermodynamics, orientational order and elasticity of strained liquid crystalline melts and elastomers
- Abstracts: Quantum state-resolved energy transfer dynamics at gas-liquid interfaces: IR laser studies of CO2 scattering from perfluorinated liquids
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