Glass formation, ionic conductivity, and conductivity/viscosity decoupling, in LiAlCl4 + LiClO4 and LiAlCl4 + LiAlCl3.imide solutions

Article Abstract:

A study on lithium salt systems investigated two factors which contribute to the establishment of a high ambient temperature conductivity in an ionic liquid. These factors are, namely, a high fluidity and a high conductivity/viscosity decoupling index. One aim of the study was to discover factors that determine the decoupling index on one hand and the glass transition temperature and fragility on the other hand for liquid salt mixtures which do not crystallize at ambient temperature.

Lithium, Lithium (Metal), Salts

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Dynamics in ionic solutions - revisited

Article Abstract:

The static and dynamic aspects of ion-probe interactions are studied using steady-state emission, absorption and time-resolved fluorescence measurements of coumarin 153 in butyl acetate - LiClO4 solutions.

Coumarins

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On the calculation of the absolute solvation free energy of ionic species: application of extrapolation method to the hydroxide ion in aqueous solution

Article Abstract:

Research is presented describing the study of ionic species to determine levels of free energy absolute solvation using extrapolation techniques.

Observations, Solvation, Nuclear polarization, Polarization (Nuclear physics)

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