Saturation of hydrogen sorption in Zn benzenedicarboxylate and Zn napthalenedicarboxylate
Article Abstract:
Excess hydrogen saturation values from high-pressure isolation of metal organic framework structures taken at 77 K are reported. Zn benzenedicarboxylate (IRMOF-1) and Zn napthalenedicarboxylate (IRMOF-8) linker structures show identical saturation values of 137 hydrogen molecules on a per unit cell basis, despite the higher sorption potential of IRMOF-8 of 6.1 kJ/mol over that of IRMOF-1 of 4.1 kJ/mol.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
User Contributions:
Comment about this article or add new information about this topic:
Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction
Article Abstract:
The catalytic mechanisms of transition-metal compounds during the hydrogen sorption reaction of magnesium-based hydrides are examined using various techniques. The results have helped in the optimization of the selection of catalysts for improving sorption properties of magnesium-based hydrides and in the utilization of transition-metal compounds as catalysts for other hydrogen storage materials.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Interaction of the acid soap of triethanolamine stearate and stearic acid with water. Monolayer characteristics of mixed octadecylamine and steric acid at the air/water interface
- Abstracts: Atomic hydrogen storage in carbon nanotubes promoted by metal catalysts. Effect of chemical treatment on electrical conductivity, infrared absorption and Raman spectra of single-walled carbon nanotubles
- Abstracts: A Poisson-Boltzmann study of charge insertion in an enzyme active site: the effect of dielectric relaxation. Electrostatic free energy calculations for macromolecules: a hybrid molecular dynamics/continuum electrostatics approach
- Abstracts: Iron silicide root formation in Carbon nanotubes grown by microwave PECVD. Thermogravimetric analysis of synthesis variation effects on CVD generated multiwalled carbon nanotubes
- Abstracts: Comparison of all sites for Ti substitution in zeolite TS-1 by an accurate embedded-cluster method. Quantitative measurement of the Bronsted acid sites in solid acids: Toward a single-site design of Mo-modified ZSM-5 zeolite