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Organometallic fluorides: compounds containing carbon-metal-fluorine fragments of d-block metals

Article Abstract:

Organometallic fluorides, containing metal atoms bonded with both fluorine and carbon, are useful in catalytic and synthetic chemistry. Despite the presence of strong metal-fluorine bonds, organometallic fluorides can be highly reactive. Organometallic fluorides are used in the production of transition metal complexes with open coordination sites, promoting catalytic reactions. Organometallic fluorides with weakly coordinating anions are useful in the development of chiral Lewis acids.

Author: Roesky, Herbert W., Murugavel, Ramaswamy, Murphy, Eamonn F.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1997
Analysis, Production management, Usage, Materials, Catalysis, Transition metal compounds, Organofluorine compounds, Organic fluorine compounds

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Organometallic hydroxides of transition elements

Article Abstract:

The synthetic procedures and structural characterizations of environmentally friendly organometallic hydroxides are reviewed. It is observed that hydroxo complexes of transition metals are postulated as critical intermediates in a number of catalytic reactions involving water as a substrate.

Author: Hosmane, Narayan S., Roesky, Herbert W., Singh, Sanjay, Yusuff, K.K.M., Maguire, John A.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2006
All Other Basic Organic Chemical Manufacturing, Texas, Industrial Organic Chemicals, Organometals, Transition metals, Hydroxides, Chemical properties

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Subjects list: Organometallic compounds
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