Allylic amination
Article Abstract:
Several allylic amination reactions representing the preparation of allylamines were discussed. Diimido compounds can be used to prepare a series of alkenes by allylic amination. Allylamines can also be determined using alkenes supporting allylic C-H bonds as the substrate. It is anticipated that reactions can be developed wherein alkenes can react with nitrogen fragment donors in the presence of chiral catalysts.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1998
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Recent advances in asymmetric catalytic metal carbene transformations
Article Abstract:
The catalytic metal carbene transformations are important in analyzing organic synthesis. These transformations with diazoacetates and diazoacetamides are characterized by a high enantiocontrol feature. The variety of metal compounds, which act as catalysts for diazo decomposition, seem to be inapplicable in transformation. Only rhodium is found to show general applicability for the process.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1998
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