Allen J. Bard

Article Abstract:

Photoelectrochemist Allen J. Bard ws born in New York City, NY, on Dec 18, 1933. Bard studied at the Bronx High School of Science from 1948 to 1951 before he enrolled at the City College of New York in Jan 1951 and at the Harvard university in Sep 1955. He started his career at the General Chemical Co in Morristown, NJ. He then joined the faculty of the University of Texas, Austin, in 1958. Bard received several and lectureships, including the 1992 G.M. Kosalapoff Award and the 1998 Linus Pauling Medal.

Biography, Chemists, Bard, Allen J.

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Electrochemical growth of Ag2S on Ag(111) electrodes. Coulometric and x-ray photoelectron spectroscopic analysis of the stepwise formation of the first and second monolayers of Ag2S

Article Abstract:

Slow-scan voltammetric experiments were carried out to demonstrate that the stepwise electrochemical growth of the first and second monolayers of Ag2S on Ag(111) electrodes in aqueous hydrosulfide solutions can be seen as well-defined waves. The two monolayers have similar structures based on x-ray photoelectron spectroscopy and coulometric analysis. However, they have different free energies of formation since oxidative formation occurs at various electrode potentials.

Research, Growth, Crystals, Thin films, Monomolecular films, Crystallization, Silver compounds, Crystal growth

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Electrochemistry of nanospore electrodes in low ionic strength solutions

Article Abstract:

A study to investigate the steady-state voltammetric behavior of truncated conical nanopore electrode is conducted in low ionic strength solutions. The anomalous values of the voltammetric half-wave potential observed at very small nanopore electrodes are ascribed to a boundary potential between the pore interior and bulk solution.

Analysis, Oxidation-reduction reaction, Oxidation-reduction reactions, Ionic solutions, Electrodes, Chemical properties

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