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Chemicals, plastics and rubber industries

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New aspects of the low-concentrated aniline polymerization in the solution and in SiC nanocrystals dispersion

Article Abstract:

The simultaneous in-situ ultraviolet-visible (UV-vis) and open-circuit potential (OCP) monitoring of the low-concentrated aniline (An) polymerization in the presence of camphorsulfonic acid (CSA) has shown that a transition state is formed during the induction period (IP) step. The results have shown that an addition of the SiC dispersion phase into the polymerization mixture has accelerated differently at all stages of the aniline polymerization.

Author: Makowska-Janusik, M., Pud, A.A., Noskov, Yu. V., Kassiba, A., Fatyeyeva, K.Yu., Ogurtsov, N.A., Bednarski, W., Tabellout, M., Shapoval, G.S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
All Other Basic Inorganic Chemical Manufacturing, Cyclic crudes and intermediates, Cyclic Crude and Intermediate Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Aniline, Silicon Carbide, Silicon carbides

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Chemical oxidative polymerization of safranines

Article Abstract:

The characterization and synthesis of safranine and phenosafranine polymers in aqueous solutions by the standard chemical oxidate polymerization route are presented. The findings suggest that besides prevalent unoxidized monomeric units, polymerization products of safranines have imonoquinonoid and newly formed fused phenazine units.

Author: Trchova, Miroslava, Stejskal, Jaroslav, Ciric-Marjanovic, Gordana, Blinova, Natalia V.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
Usage, Fourier transform infrared spectroscopy, Sulfates, Ammonium compounds, Ammonium chloride, Ammonium paratungstate, Ammonium salts

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Subjects list: Research, Polymerization, Chemical properties, Report
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