Controlled amine functionality in self-assembled monolayers via the hidden amine route: Chemical and electric tunability

Article Abstract:

A synthetic strategy for fabricating a dense amine functionalized self-assembled monolayer (SAM) on hydroxylated surfaces is presented. A new approach for obtaining SAM with amine functionality on hydroxylated surfaces using the formation of a dense monolayer of alkylbromide- trichlorosilane and transformation of the bromine moiety to amine by a two-step procedure is concluded.

Monomolecular films, Surface chemistry, Amines, Chemical properties

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Energy transfer at a gas-liquid interface: Kinematics is a prototypical system

Article Abstract:

Various simulations of prototypical Lennard-Jones system are performed to study the energy transfer dependence on the strength of the gas-liquid interaction. The analysis shows that the kinetic effects and surface roughening play a very important role in the enhancement of energy transfer accompanied by increase in the liquid temperature.

Transition state (Chemistry), Energy transformation

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