Electronic structure of a chemisorbed layer at electrochemical interface: copper layer on gold electrode

Article Abstract:

A model Hamiltonian is constructed to describe an electrochemisorbed layer. The proposed model, which is a generalized version of the Anderson-Newns Hamiltonian, can be used for a random adsorbate layer with arbitrary coverage and the ensuing two-dimensional band formation by metallic adsorbates in the monolayer regime. This model Hamiltonian is tested on the electrosorption of copper ion on gold electrode and used to determine coverage dependence of adsorbate charge, binding energy, adsorbate density of states.

Models, Copper, Gold, Adsorption

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Electrochemically induced dynamics of a benzylic amide [2]catanane

Article Abstract:

An investigation into the electrochemistry of benzylic amide[2]catenane is presented together with a comparison with its topologically trivial components.

Molecules

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