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Debundling of single-walled nanotubes by dilution: Observation of large populations of individual nanotubes in amide solvent dispersions

Article Abstract:

Atomic force microscopy (AFM), ultraviolet (UV)-vis-near infrared (NIR) absorption, NIR photoluminescence and Raman spectroscopy are used to demonstrate that single-walled nanotubes can be debundled simply by reducing the nanotube concentration in N-methyl-2-pyrrolidone (NMP) dispersions. The findings reveal that the average bundle diameter decreases with decreasing concentration of 8 x [10.sup.-3] mg/mL.

Author: Lebedkin, Sergei, Kappes, Manfred M., Coleman, Jonathan N., Blau, Werner J., Giordani, Silvia, Bergin, Shane D., Nicolosi, Valeria
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Analysis, Observations, Optical properties, Infrared spectroscopy, Atomic force microscopy, Structure, Nanotubes, Pyrrole, Pyrroles

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Binding kinetics and SWNT bundle dissociation in low concentration polymer-nanotube dispersions

Article Abstract:

A new spectroscopic method is described in this work, to measure the ratio of free polymer to nanotube-bound polymer in SWNT/polymer solutions. This ratio is highly nonlinear and can be described by a model based on polymer-nanotube adsorption/desorption kinetics.

Author: Coleman, Jonathan N., Blau, Werner J., Fleming, Alexander, Maier, Stefanie, Minett, Andrew L., Hutzler, Stefan, O'Flaherty, Sean, Ferreira, Mauro S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Science & research, Research, Methods, Polymers, Adsorption, Dynamics, Dynamics (Mechanics)

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Subjects list: Chemical properties
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