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Chemicals, plastics and rubber industries

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Dependence of copper species on the nature of the support for dispersed CuO catalysts

Article Abstract:

Copper catalysts prepared by chemisorption-hydrolysis technique over silica (Cu/Si) and silica- alumina (Cu/SiAl) supports are studied to understand the role of the support on the nature and surface properties of the copper species stabilized on their surfaces. Results indicate that the deposition of copper by using the same 'chemisorption- hydrolysis' method resulted in different supported species if silica or silica-alumina are employed as support.

Author: Martra, Gianmario, Gervasini, Antonella, Ravasio, Nicoletta, Zaccheria, Federica, Sordelli, Laura, Manzoli, Maela, Ponti, Alessandro
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Industrial sand, Silica & Silica Sand, Industrial Sand Mining, Silica, Hydrolysis, Copper compounds, Chemical properties, Silicon dioxide

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Experimental and modelization approach in the study of acid-site energy distribution by base desorption: Part I: Modified silica surfaces

Article Abstract:

The acid properties of pure and modified silica surfaces were examined in a study by 2-phenylethylamine (PEA) desorption in a thermogravimetric (TGA) apparatus. The chemical modification of the silica surface by enrichment with Al, Ti, or Zr justified the increase of acidity of the modified silica surfaces compared with that of pure silica.

Author: Bennici, Simona, Gervasini, Antonella, Carniti, Paolo
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Silicon & Inorganic Compounds, Zirconium, Aluminum Compounds, Electric properties, Titanium compounds, Thermogravimetry, Silicon compounds

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Subjects list: Analysis
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