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Chemicals, plastics and rubber industries

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Deposition of nanostructured fluoropolymer films on silicon substrates via plasma polymerization of allylpentafluorobenzene

Article Abstract:

Nanoporous and highly hydrophobic fluoropolyme films composed of nanospheres are deposited on the oxide-covered and hydrogen-terminated Si(100) surfaces via plasma polymerization of allypentafluorobenzene (APFB). The chemical composition and structure, as well as the physical morphology of the plasma polymerized APFB (pp-APFB) films could not be controlled to a large extent by the glow discharge conditions.

Author: E.T. Kang, G.D. Fu, Neoh, K.G.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Semiconductors and related devices, Semiconductor and Related Device Manufacturing, All Other Basic Inorganic Chemical Manufacturing, Thin Film Materials, Industrial inorganic chemicals, not elsewhere classified, Silicon, Thin films, Dielectric films

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Plasmachemical amine functionalization of porous polystyrene spheres: The importance of particle size

Article Abstract:

It is observed that allylamine plasma functionalization of porous polystyrene spheres is dependent on particle size. A combination of Fmoc derivatization and cross-sectional Raman microscopy shows that an outer layer of approximately 3-4 mum can be selectively functionalized to yield relatively high amine group loadings.

Author: Badyal, J.P.S., Oye, G., Roucoules, V., Oates, L.J., Cameron, N.R., Cameron, A.M., Steel, P.G, Davis, B.G, Coe, D.M, Cox, R.A.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Polystyrene, Styrene Resins, Polystyrene Resins NEC, Amines

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Super-repellent composite fluoropolymer surfaces

Article Abstract:

Water repellency enhances due to deposition of low surface plasma polymer layers and expanded PTFF substrate. The Casse-Baxter relationship was found to be more appropriate.

Author: Badyal, J.P.S., Coulson, S.R., Woodward, I., Brewer, S.A., Willis, C.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
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Subjects list: Research, Chemistry, Physical and theoretical, Physical chemistry, Chemical properties, Fluoropolymers
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