Experimental and computational investigation of the energetics of the three isomers of monochloroaniline

Article Abstract:

The standard molar enthalpies of formation of 2-3-, and 4-chloroaniline were derived from the standard molar energies of combustion, in oxygen, at T=298.15 K, measured by rotating bomb combustion calorimetry. The Calvet high-temperature vacuum sublimation technique was used to measure the enthalpies of vaporization or sublimation of the three isomers.

Enthalpy, Isomerism, Isomers (Chemistry)

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Interference of ascorbic acid in the sensitive detection of dopamine by a nonoxidative sensing approach

Article Abstract:

Studies of the electrochemistry of a poly(anilineboronic acid)/carbon nanotube composite which was carried out in presence of dopamine and ascorbic acid is described. It would benefit the design of a wide variety of boronic acid-based biosensors with high sensitivity and selectivity.

Usage, Electric properties, Fluorescence, Vitamin C, Dopamine, Nanotubes

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Experimental and computational study of the thermochemistry of the fluoromethylaniline isomers

Article Abstract:

The comparison results of the standard molar enthalpies of formation of fluoromethylaniline in gaseous state with the Cox scheme and the G3MP2/B3LYP calculations are presented.

Analysis, Thermal properties, Fluorine compounds, Chemical thermodynamics

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