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Chemicals, plastics and rubber industries

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In situ STM study of chloride adsorption on Cu(110) electrode in hydrochloride acid aqueous solution

Article Abstract:

In situ scanning tunneling microscopy (STM) was employed for investigating the adsorption of chloride on copper(110) (Cu) single-crystal surface in hydrochloride aqueous solution. High resolution STM images revealed that the coexisting (4 x 1) and (5 x 1) adlayer structures in the potential range from -400 mV to -150 mV were produced by the chloride adsorbed on the Cu(110) surface.

Author: Wang, Y., Yide Xu, Xinhe Bao, Li, W.H., Ye, J.H., Li, S.F.Y.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
Usage, Scanning tunneling microscopy, Copper compounds, Aqueous solution reactions, Chemical properties

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Study on conformation interconversion of 3-alkyl-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines from dynamic NMR experiments and ab initio density functional calculations

Article Abstract:

Variable-temperature NMR experiments and ab intio density functional calculations were carried out to investigate the conformation interconversion of novel chiral 3-alkyl-3,4-dihydro-2H-benzo[1,4]oxazine derivatives. The changing tendencies of the calculated activation free energies and interconversion rates agreed well with those of the NMR results.

Author: Xiuwen Han, Xinhe Bao, Xiumei Liu, Weiping Zhang, Gang Yang, Pengyu Yang, Yonggui Zhou
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Analysis, Nuclear magnetic resonance spectroscopy, Spectra, Density functionals, Density functional theory, Alkyl groups

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