Lability of a mixture of metal complexes under steady-state planar diffusion in a finite domain

Article Abstract:

A methodology to determine the effect of a ligand mixture on the contribution of the complexes to the metal flux in systems under diffusion-limited conditions in a planar finite domain for any value of the association/dissociation rate constants is developed. The results have shown that the mixture effect can lead to an increase or decrease of the degree of lability of a complex in a mixture and can have a major impact on the metal flux, especially under conditions that render both complexes partially labile.

Science & research, Research, Ligands, Ligands (Chemistry), Flux (Metallurgy), Properties, Structure

---

Transport properties in ionic liquids and ionic liquid mixtures: The challenges of NMR pulsed field gradient diffusion measurement

Article Abstract:

The data results from studies conducted shows that the pulsed gradient spin echo (PGSE) method suffers from intrinsic internal gradients and could produce apparent diffusion coefficients which vary by as much as 20% for different [super 1]H nuclei within a given molecule.

Usage, Nuclear magnetic resonance, Ionic solutions, Chemical properties

---

Mass transport model for semiconductor nanowire growth

Article Abstract:

A mass transport model based on surface diffusion for metal-particle-assisted nanowire growth is presented. The results demonstrate that the Gibbs-Thomson effect can be neglected for III/V nanowires grown at conventional temperatures and pressures.

Semiconductors, Thermal properties, Gibbs' equation, Semiconductors (Materials)

Similar abstracts:

• Abstracts: The reactivity of all-metal aromatic complexes: A theoretical investigation on the methane activation reaction
• Abstracts: Factors governing the metal coordination number in metal complexes from Cambridge structural database analyses
• Abstracts: Catalytic ignition of H2/O2 mixtures on platinum: ignition temperatures and postignition transients. Determination of adsorption and desorption parameters from ignition temperature meausrements in catalytic combustion systems
• Abstracts: Dynamics of water in the hydration shells of [C.sub.60]: molecular dynamics simulation using a coarse-grained model
• Abstracts: Phase separation of a model binary polymer solution in an external field

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.