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Liquid phase behavior of ionic liquids with alcohols: Experimental studies and modeling

Article Abstract:

The effect of chemical and structural factors on the phase behavior of ionic liquids with alcohols is examined, focusing on pyridinium ionic liquids (ILs) for comparison to imidazolium ILs from previous studies. The nonrandom two-liquid (NRTL) equation with binary interaction parameters with linear temperature dependence has provided a good fit of the experimental data for all the systems.

Author: Maginn, Edward J., Brennecke, Joan F., Crosthwaite, Jacob M., Aki, Sudhir N.V.K., Muldoon, Mark J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Analysis, Phase transformations (Statistical physics), Phase transitions (Physics), Structure

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Liquid phase behavior of ionic liquids with alcohols: Experimental studies and modeling

Article Abstract:

The effect of chemical and structural factors on the phase behavior of ionic liquids with alcohols is examined, focusing on pyridinium ionic liquids (ILs) for comparison to imidazolium ILs from previous studies. The nonrandom two-liquid (NRTL) equation with binary interaction parameters with linear temperature dependence has provided a good fit of the experimental data for all the systems.

Author: Maginn, Edward J., Brennecke, Joan F., Crosthwaite, Jacob M., Aki, Sudhir N.V.K., Muldoon, Mark J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Pyridinium compounds

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Liquid phase behavior of imidazolium-based ionic liquids with alcohols

Article Abstract:

The impact of different characteristics of the ionic liquids (ILs) and the alcohols on the liquid-liquid phase equilibrium of imidazolium-based ionic liquids and alcohols is examined. The ionic liquid-water mutual solubility data for a number of ionic liquids is discussed.

Author: Maginn, Edward J., Brennecke, Joan F., Crosthwaite, Jacob M., Aki, Sudhir N.V.K.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Industrial Organic Chemicals, Cyclic Crude and Intermediate Manufacturing, Imidazole, Behavior, Properties

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Subjects list: Ionic solutions, Alcohols, Chemical properties, Research
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