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Chemicals, plastics and rubber industries

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Potential dependence of electron-transfer rates at the interface between two immiscible electrolyte solutions: reduction of 7,7,8,8-tetracyanoquinodimethane in 1,2-dichloroethane by aqueous ferrocyanide studied with microelectrochemical techniques

Article Abstract:

Research is presented describing the use of microelectrochemical measurements at expanding droplets and scanning electrochemical microscopy to analyse the interface between two immiscible electrolyte solutions' electron transfer reactions.

Author: Unwin, Patrick R., Zhang Jie
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Electrolyte solutions, Chemical reaction, Rate of, Chemical kinetics, Electrochemical analysis

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In situ observation of the surface process involved in dissolution from the (010) surface of potassium ferrocyanide trihydrate in aqueous solution using an integrated electrochemical-atomic force microscope

Article Abstract:

Research is presented concerning the use of an integrated electrochemical-atomic force microscope to investigate the surface chemistry resulting from the dissolution, in aqueous solution, of the (010) surface of potassium ferrocyanide trihydrate.

Author: Unwin, Patrick R., Jones, Claire E., Macpherson, Julie V.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Electrochemical apparatus, Potassium salts, Electrochemical instruments

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Kinetics of O2 reduction at illuminated TiO2 films

Article Abstract:

The channel flow method with electrochemical detection was used to investigate the photoelectrochemical reduction of O2 at UV-illuminated TiO2 surfaces in both aerated and oxygenated solutions. The kinetics of the reduction process was reported, and the implications for semiconductor photocatalysis were discussed.

Author: Unwin, Patrick R., Ahmed, Samina, Fonseca, Sofia M., Kemp, Terence J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, Oxygen, Industrial Gas Manufacturing, Industrial gases, Electric properties, Titanium dioxide, Chemical properties

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Subjects list: Research, Usage, Oxidation-reduction reaction, Oxidation-reduction reactions, Chemistry, Physical and theoretical, Physical chemistry, Surface chemistry, Chemical microscopy
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