Predictions of conformational enthalpy and heat capacity from the Zimm-Bragg theory

Article Abstract:

The study was done on the conformational enthalpy and heat capacity of a solution pf poly-gamma-benzyl-L-glutamate using the partition function of Zimm-Bragg for helix-coil transitions. The temperature dependence of the statistical parameter s from optical data is determined and treat the parameter rho- as a fitting parameter.

Science & research, Analysis, Glutamate, Transition temperature, Chemical properties, Phase transition temperatures

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Statistical-mechanical approach to the thermodynamic functions in the unfolding of biomolecules

Article Abstract:

The statistical-mechanical formulation for calculating heat capacity and enthalpy functions in conformational changes of biomolecules is extended to include free-energy and entropy functions. The results are compared with published experimental values and are in reasonably good agreement with the measured results.

Observations, Thermodynamics, Mechanical properties

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Statistical mechanical approach to the conformational heat capacity and enthalpy of biomolecules

Article Abstract:

Research of the determination of heat capacity and enthalpy changes associated with temperature in conformational biomolecular transitions using a statistical mechanical approach is presented.

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