Raman micro spectrometry as a new approach to the investigation of molecular recognition in solids: chlorofornm-cryptophane complexes

Article Abstract:

A polarized Raman micro spectrometry study of micro crystals of cryptophane-A, selectively deuterated cryptophane-A, bis-cryptophane, and cryptophane-E encapsulating chloroform molecules is presented. By x-ray diffraction analysis, the crystallographic structures of these different molecular entities are isolated.

Molecular structure

---

Kinetics of molecular transport in a nanoporous crystal studied by confocal Raman microspectrometry: single-file diffusion in a densely filled tunnel

Article Abstract:

Confocal Raman microspectrometry is used for probing the kinetic aspects of the guest exchange process in a urea inclusion compound. The transport of the new pentadecane guest molecules along the tunnel has displayed a linear dependence on time, with the rate of the process in the region of 70-100 nm [s.sup.-1].

All Other Basic Inorganic Chemical Manufacturing, Nitrogenous Fertilizer Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Zeolites, Nitrogenous fertilizers, Urea, Spectra, Dynamics, Dynamics (Mechanics), Mechanical properties, Structure

---

Distribution of hydrophobic ions and their counterions at an aqueous-liquid-liquid interface. A molecular dynamics investigation

Article Abstract:

The molecular dynamics study on the distribution of spherical hydrophobic ions and hydrophilic counterions at a water-'oil' surface, where 'oil' is modeled by chloroform is discussed. Also discussed are the implications of the results of the mechanism of assisted ion transfer.

Molecular dynamics, Electrochemistry, Hydrophobic effect

Similar abstracts:

• Abstracts: Computational investigation of adsorption of molecular hydrogen on lithium-doped corannulene. Theoretical analysis of oxygen adsorption on Pt-based clusters alloyed with Co, Ni, or Cr embedded in a Pt matrix
• Abstracts: Metal ionchromic effects of conjugated polymers: Effects of the rigidity of molecular recognition sites on metal ion sensing
• Abstracts: An FT-Raman spectroscopic study of the conformational properties of chlorocyclohexane in zeolites. An FT-Raman spectroscopic study of the conformational behavior of trans-1,4-dichlorocyclohexane adsorbed in zeolites
• Abstracts: An X-ray absorption spectroscopy investigation of the formation of FeCo alloy nanoparticles in Al2O3 xerogel and aerogel matrixes
• Abstracts: Excitation decay pathways of Lhca proteins: A time-resolved fluorescence study. Ultrafast polarized fluorescence measurements on tryptophan and a tryptophan-containing peptide

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.