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Sorption and pore condensation behavior of nitrogen, argon, and krypton in mesoporous MCM-48 silica materials

Article Abstract:

Results of a systematic study on the sorption- and phase behavior of nitrogen, argon, and krypton at 77 and 87 K in different pristine mesoporous MCM-48 silica phases (BJH pore diameters 2-3nm) and MCM-48 silica iron(III) host compound are presented. Different methods were used to analyze nitrogen (77 K) and argon (87 K) sorption isotherms in order to characterize the MCM-48 silica materials with respect to surface area, pore volume and pore diameter.

Author: Kohn, Ralf, Thommes, Matthias, Froba, Michael
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Krypton

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Effect of argon plasma treatment on surface-enhanced Raman spectroscopy of polypyrrole deposited on electrochemically roughened gold substrates

Article Abstract:

Polypyrrole (PPy) films were electrodeposited on electrochemically roughened gold substrates modified by argon plasma treatment. The surface-enhanced Raman scattering (SERS) spectroscopy of polypyrrole electrodeposited on this roughened gold substrate modified by argon plasma treatment exhibits a higher intensity by 8-fold, as compared with the SERS of PPy electrodeposited on an unmodified roughened gold substrate.

Author: Yu-Chuan Liu, Chee-Chan Wang
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Gold Compounds, Electrochemistry, Raman effect

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SANS investigation of nitrogen sorption in porous silica

Article Abstract:

The analysis of the small-angle neutron scattering (SANS) data shows that the mean size of the remaining empty mesopores formally increases, and their size distribution becomes narrower during capillary condensation. The combination of SANS and nitrogen sorption was used to elucidate the mechanism of nitrogen sorption in different meso- and microporous silicas with regular as well as disordered pore structures.

Author: Smarsly, Bernd, Goltner, Christine, Antonietti, Markus, Ruland, Wilhelm, Hoinkis, Ernst
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
Chemistry, Physical and theoretical, Physical chemistry, Sorption

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Subjects list: Electric properties, Silica, Nitrogen, Argon, Research, Chemical properties
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