The structure of a trimolecular liquid: tert-Butyl alcohol:cyclohexene:water

Article Abstract:

The structure of the trimolecular liquid mixture of 2:6:1 cyclohexene, tert-butyl alcohol, and water is investigated using hydrogen/deuterium substitution neutron scattering techniques, and a three-dimensional structural model refined to be consistent with the experimental data. Cyclohexene molecules favor direct solvation by alcohol methyl groups, while water molecules are accommodated, dispersed throughput the solution, through hydrogen bonding interactions with the alcohol molecule hydroxyl groups.

All Other Basic Organic Chemical Manufacturing, Industrial Organic Chemicals, Tertiary Butanols, Water, Structure, Butanol, Tertiary butyl alcohol

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Experimental and theoretical studies on structure-reactivity relationships of titanium-modified silicaEs in the hydrogen peroxide-promoted oxidation of cyclohexene

Article Abstract:

Experiments were done on several catalysts containing different organic ligands bonded to the titanium centers that were prepared, characterized and tested in the benchmark reaction of cyclohexene with hydrogen peroxide. The results show that the activity and selectiveness of the catalysts depend on the relative basicity of the ligands and their variation is proportional to the calculated Lewis acidity.

Industrial sand, Silica & Silica Sand, Industrial Sand Mining, Analysis, Silica, Structure-activity relationships (Biochemistry), Oxidation-reduction reaction, Oxidation-reduction reactions, Properties, Silicon dioxide

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Displacement of ethene and cyclohexene from polycrystalline Pt and Pt(110) electrodes

Article Abstract:

The adsorbate formed after adsorption of cyclohexene on Pt(110) and polycrystalline Pt electrodes is displaced by competitive adsorption of UPD copper. Since it desorbs as benzene, cyclohexene is dehydrogenated during adsorption.

Electrodes, Chemical compounds

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