Voltammetry under microfluidic control: computer aided design development and application of novel microelectrochemical reactors

Article Abstract:

The development, numerical quantification and application of microelectrochemical reactors (MECR) are described. The response of a range of MECR devices with varying dimensions is examined and the finite element method to calculate the transport-limited current as a function of the volume flow rate is used.

Fluid dynamics, Electrochemistry, Voltammetry

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A Kirkwood-Buff derived force field for mixtures of urea and water

Article Abstract:

A study conducted reveals that a realistic model for urea and water mixtures can be obtained by using the Kirkwood-Buff theory. The model displays little or no urea self-aggregation in agreement with the experimental data.

Nitrogenous Fertilizer Manufacturing, Nitrogenous fertilizers, Urea, Water, Molecular dynamics, Chemical properties

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Underpotential deposition of metals from thermodynamic and structural considerations.2. nonaqueous solvents

Article Abstract:

The under-potential deposition shifts of a few redox metallic couples in nonaqueous solvents are estimated. The parameters required for this are lattice coordination numbers and desorption energies of solvent dipoles.

Thermal properties, Thermodynamics, Surface chemistry, Superlattices as materials, Superlattices

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