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Structure and spectroscopy of copper-dioxygen complexes

Article Abstract:

The structures and spectroscopic properties of well-characterized copper dioxygen (CU/O2) species formed by the reaction of Cu(I) complexes with O2 are reported. The objective is to highlight the ligand attributes that create O2-reactive Cu(I) complexes and lead to specific types of Cu/O2 species.

Author: Mirica, Liviu M., Ottenwaelder, Xavier, Stack, T. Daniel P.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Oxygen, Optical properties, Copper compounds, Structure

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N, NE-dicyanoquinone diimines (DCNQIs): Versatile acceptors for organic conductors

Article Abstract:

The temperature- and pressure dependent conductivities of the anion radical salts [2-X, 5-Y-DCNQI](sub 2]M are studied by physical methods. The interplay between densities of charge carriers and their mobility is modified by the substituents X and Y and by the metal ions.

Author: Hunig, Siegfried, Herberth, Edith
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Nitrogen, Electric properties, Anions

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