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Hemiporphyrazines as targets for the preparation of molecular materials: synthesis and physical properties

Article Abstract:

Hemiporphyrazines are four-unit macrocycles which contain two opposite-faced units and two other hetero-aromatic moeities which are bound through aza bridges. These compounds are considered building blocks of molecular materials. Because of their high synthetic versatility, the compounds' physical properties such as electrical and optical can be easily analyzed. The compounds can also be utilized in the preparation of two-dimensional metal with potential electrical and magnetic properties.

Author: Torres, Tomas, Hanack, Michael, Fernandez-Lazaro, Fernando, Hauschel, Bernd
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1998
Polymers, Organic compounds, Organic compound synthesis, Polycyclic compounds

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Phthalocyanines-versatile components of molecular conductors

Article Abstract:

Pc based conductors with clearly defined structures are described. It is revealed that Pc based conductors had rather unique properties as a 1D system. It is found that the electronic properties at low temperature were severely affected by the defects or impurities in the crystal due to their highly one-dimensional electronic structure.

Author: Inabe, Tamotsu, Tajima, Hiroyuki
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Science & research, Electric properties, Electrons

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Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds

Article Abstract:

Major advances are made in the design and synthesis of phathalocyanines and related materials for nonlinear optical (NLO). The results obtained on the correlation between molecular structure and NLO response is summarized and some strategies for rendering new systems with improved NLO properties are provided.

Author: Agullo-Lopez, F., Torre, Gema de la, Vazquez, Purificacion, Torres, Tomas
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Analysis, Molecular structure, Nonlinear optics

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Subjects list: Research, Optical properties, Phthalocyanins
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