Model studies in catalysis using surface science probes

Article Abstract:

A procedure which unites ultrahigh vacuum surface analytical methods with an elevated pressure reactor can open new vistas of knowledge about the molecular details which explain and regulate the process of reactions at the gas/solid interface. These techniques can provide an understanding of the basic concepts of heterogeneous catalysis such as structure sensitivity and structure insensitivity. Model single-crystal catalysts and oxide-supported metal catalysts are presented and their abilities and limits are discussed in detail.

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Asymmetric enamine catalysis

Article Abstract:

A significant growth and advancement observed in asymmetric enamine catalysis which uses wide range of nucleophiles such as ketones, aldehydes and prolines is reviewed.

Schiff bases, Chemical properties

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Asymmetric catalysis of chiral metal surfaces

Article Abstract:

The article discusses the synthesis and the properties of the chiral metal surfaces, which are commonly employed in enantioselective catalysis.

Observations, Chirality, Metals, Metal surfaces

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