Polyoxoanion chemistry moves toward the future: from solids and solutions to surfaces

Article Abstract:

The understanding of early metal polyoxoanion chemistry has progressed rapidly, which is driven by the advances in catalytic instrumentation. However, its development was not matched by a progress in the research of surface chemistry as surface analytical tools have only just been recently discovered and their full potential are yet to be exploited. The equipment include the quartz crystal microbalance, the modulated infrared spectroscopy and the scanning probe microscopy.

Inorganic compounds

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Photo- and electrochromism of polyoxometalates and related materials

Article Abstract:

A study on electron transfer and energy transfer within polyoxometalates and related metal oxide solids is presented. The methods photochromism and electrochromism are used to observe the coloring behavior of metal oxides and polyoxometalate solids. Results show that the photochromic and electrochromic coloration of polyoxometalate and related metal oxide lattices is triggered by the trappings of d(sub1) electrons at appropriate metal sites.

Analysis, Photochemical research, Electrochemistry

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Recognition and reaction of metallointercalators with DNA

Article Abstract:

Metallointercalators could be used to probe DNA structures and even prevent genetic transcription. These compounds are flat planar structures that can intercalate between nucleotide residues.

Clathrate compounds

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