Silylphosphanes: developments in phosphorous chemistry

Article Abstract:

The development of the chemistry of molecular compounds with Si-P bonds, silylphosphanes, as it evolved in the middle of the century to the present time is discussed. The review focuses on the structure and formation of phosphinophosphinidene phosphoranes, metal cluster compounds, the group of 13/15 semiconductors, and compounds with Si-P and P-C multiple bonds.

United States, Molecular crystals, Silicon compounds, Polycyclic compounds

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Anellated heterophospholes and phospholides and analogies with related non-phosphorous systems

Article Abstract:

This article draws an analogy between the synthesis, structures, and reactivities of the anellated heterophospholes, containing aromatic or saturated heterophosphorole ring, and those of non-phosphorous systems comprising heterocycles with one or two-coordinate phosphorous fused to five- or six- or seven-membered ring.

India, Heterocyclic compounds, Furans, Ring formation (Chemistry), Cyclization (Chemistry)

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Hydrides of the main-group metals: new variations on an old theme

Article Abstract:

This article discusses recent advances related to binary and mixed hydrides that are formed by various metal groups encompassing main metals. Research describes new precursors for the design and fabrication of multilayer devices with special electrical and optical properties and transient molecules analysis.

United Kingdom, Coordination compounds, Metal complexes (Chemistry)

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