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Templated photochemistry: Toward catalysts enhancing the efficiency and selectivity of photoreactions in homogeneous solutions

Article Abstract:

The templated photochemical reactions in a homogeneous solution, which are initiated or mediated by light, are reviewed. The findings suggest that shielding of prochiral faces, topochemical reaction control, templating, and aggregate or inclusion complex formation are strategies responsible for enhancing and controlling reaction efficiency regio- or stereoselectivity.

Author: Konig, Burkhard, Svoboda, Jiri
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2006
Analysis, Photochemical research

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Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation

Article Abstract:

The progress of homogeneous and heterogeneous catalytic chiral epoxidation is summarized to grant a convenient and wide vision for the understanding of peers working in the area of asymmetric catalysis. In several systems, there is still a large space to improve the enantioselectivity and chemoselectivity of the asymmetric epoxidations.

Author: Q.-H. Xia, H.-Q. Ge, C.-P. Ye, Z.-M. Liu, K.-X. Su
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2005

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Subjects list: Catalysts, Chirality, Chemical properties
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