Optically switchable molecular solids: photoinduced spin-crossover, photochromism, and photoinduced magnetization

Article Abstract:

A probable route, to find the new optically switchable molecular solids, is to investigate the photoeffects of compounds that exhibit an abrupt phase transition or hysterisis loop. This suggests, that the introduction of intermolecular interactions such as pie-pie interactions, hydrogen bonding or an ion-dipole interaction, might serve to achieve optical switching effects in molecular compounds.

Hydrogen bonding, Hydrogen bonds, Photochemistry, Rearrangements (Chemistry), Photochromic materials

---

Transition metal-catalyzed/mediated reaction of allenes with a nucleophilic functionality connected to the sigma-carbon atom

Article Abstract:

Allenes, which have a nucleophilic functionality, connected to the sigma-carbon atom, have been shown to be versatile building blocks for the synthesis of butenolides, lactams, iminolactones, etc. The reaction may proceed, via the carbometalation-nucleophilic attack mechanism, or the nucleo-metallation-reductive elimination.

Industrial Organic Chemicals, Cyclic Crude and Intermediate Manufacturing, Aliphatic Hydrocarbons, Alkynes, Aliphatic compounds, Ring formation (Chemistry), Cyclization (Chemistry)

---

Similar abstracts:

• Abstracts: Core-modified expanded porphyrins: new generation organic materials. Reversible binding of Oxygen to aromatic compounds

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.