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Kinetics of the laser-induced photoreduction of U(VI) in aqueous suspensions of TiO2 particles

Article Abstract:

Irradiation-induced uranium(VI) reduction to uranium(IV) in a titanium dioxide solution has been found to involve only adsorbed uranium species. Time-resolved laser-induced fluorescence was used both as a monitor and an energy source for the reaction experiments and results also show that uranium reduction is possible even in an oxygenated medium and that the mechanisms in play may also have counterparts in oxic-photic zone of surface waters.

Author: Eliet, Veronique, Bidoglio, Giovanni
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1998
Research and Development in the Physical, Engineering, and Life Sciences, Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Ecological Sciences, Uranium Metal, Industrial Water Pollution, Environmental aspects, Environmental sciences, Uranium, Titanium dioxide

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Products of the gas-phase reactions of NO3 radicals with furan and tetramethylfuran

Article Abstract:

A study showed the reaction of NO3 radicals with furan and tetramethylfuran yielded cis- and trans-butenedial as main products, with no indication of the formation of nitrates and peroxynitrates, for reaction with furan. Reaction with tetramethylfuran yielded a product that was tentatively identified as cis-3,4-dimethylhex-3-en-2,5-dione.

Author: Berndt, Torsten, Boge, Olaf, Rolle, Wolfgang
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1997
Gaseous Pollutants, Air pollution, Nitrogen oxides, Nitrogen oxide, Furans

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Subjects list: Research, Environmental chemistry
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