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Lead immobilization of from aqueous solutions and contaminated soils using phosphate rocks

Article Abstract:

The ability of phosphate rocks to immobilize lead (Pb) from aqueous solutions and contaminated soils investigated. Experiments were carried out wherein different amounts of phosphate rocks were made to react with Pb-contaminated liquid solutions and soils. An atomic absorption spectrophotometer was used to determine the total metal concentrations and the total dissolved phosphate. Results indicate that Pb immobilization was achieved due to the dissolution of phosphate rocks and the precipitation of a fluoropyromorphite-like mineral.

Author: Traina, Samuel J., Ma, Qi Ying, Logan, Terry J.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1995
Methods, Usage, Soil disinfection, Soils, Phosphate rock

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Chemical and mineralogical characterizations of Pb in a contaminated soil: reactions with synthetic apatite

Article Abstract:

An examination of the interactions of selected lead minerals and a lead-contaminated soil with apatite reveals that apatite amendments to Pb-contaminated soil materials can lead to the formation of hydroxypyromorphite (HP) after a reaction period of two days. The formation also caused substantial decreases in aqueous Pb concentrations. The extent of reaction is dependent upon pH, with more HP formation at pH 5 than at pH 6 or pH 7.

Author: Traina, Samuel J., Logan, Terry J., Laperche, Valerie, Gaddam, Pranitha
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1996
Primary nonferrous metals, not elsewhere classified, Lead, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Phosphate rock, Phosphate Rock Mining, Lead products, Environmental aspects, Nonmetal mining, Apatite, Apatites

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Oxyanion behavior in alkaline environments: sorption and desorption of arsenate in ettringite

Article Abstract:

The sorption of arsenate by ettringite is not affected when the arsenate solution is alkaline, but sorption behavior is affected by the concentration of the ettringite suspension. The main mechanisms for sorption of arsenate by ettringite appears to be channel substitution and surface complexation, at least at arsenate concentrations lower than 0.1 mM.

Author: Traina, Samuel J., Logan, Terry J., Myneni, Satish C. B., Waychunas, Glenn A.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1997
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Arsenic & Compounds, Arsenic compounds, Soil absorption and adsorption, Absorption, Soil science

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Subjects list: Research, Analysis, Lead, Soil pollution, Phosphate minerals
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