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Reactions and Applications of titanium imido complexes

Article Abstract:

The reactions and applications of titanium imido complexes are highlighted and the advances in this area are reviewed. Ti=NR linkage is shown to couple stoichiometrically with a variety of unsaturated substrates where the choice of imido N substituent is critical and a significant difference in reactivity between alkyl- and aryl- imides is observed.

Author: Hazari, Nilay, Mountford, Philip
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2005
Petroleum Refineries, Petroleum refining, Polymerization, Titanium compounds

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Chemistry of metal thio- and selenocarboxylates: Precursors for metal sulfide/selenide materials, thin films, and nanocrystals

Article Abstract:

The synthetic routes are developed for a wide variety of thermally stable metal thiocarboxylates and selenocarboxylates. The potential use of some of these compounds as single-source precursors for making metal sulfide and selenide bulk materials, thin films and nanoparticles are described.

Author: Vittal, Jagadese J., Men Tack Ng
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2006
Sulfides, Carboxyl compounds

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Polyhedral oligomeric silsesquioxane nanocomposites: The next generation material for biomedical applications

Article Abstract:

The properties of nanocomposites, which are creating the revolution in material science, are studied. It is analyzed that the new generation of silica nanocomposites, polyhedral oligomeric silsesquioxanes, a nanoscale silica particle is used in cardiovascular devices with a particular use.

Author: Kannan, Ruben Y., Salacinski, Henryk J., Butler, Peter E., Seifalian, Alexander M.
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2005
Catalysis, Properties, Nanoparticles

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Subjects list: United Kingdom, Analysis, Stoichiometry, Structure, Chemical properties, Chemical synthesis
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