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Scientific basis for process and catalyst design in the selective oxidation of Methane to Formaldehyde

Article Abstract:

The mechanism and kinetics of the gas-phase selective oxidation of methane to formaldehyde (MPO) in context of catalytic oxidations are reviewed. Langmuir-Hinshelwood kinetic model is suggested for the steady-state conditions and activity-selectivity pattern of MPO catalysts.

Author: Arena, Francesco, Parmaliana, Adolfo
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2003
United States, All Other Basic Organic Chemical Manufacturing, Industrial organic chemicals, not elsewhere classified, Formaldehyde, Methane, Oxidation-reduction reaction, Oxidation-reduction reactions

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Theory of asymmetric organocatalysis of aldol and related reactions: rationalizations and predictions

Article Abstract:

Classic and contemporary asymmetric reactions involving organocatalysts can be studied with models. This study will now become a common procedure to find more efficient methods to search complex conformational spaces, faster computers and improved algorithms.

Author: Alleman, Christophe, Gordillo, Ruth, Cheong, Paul Ha-yeon, Houk, K.N.
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
Chemical reactions, Amino acids, Chemical properties

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Subjects list: Research, Catalysts
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