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Alfred Werner revisited: The coordination chemistry of anions

Article Abstract:

A series of macrocyclic receptors are designed to probe the influence of four factors, hydrogen bonding, charge, dimensionality, and topology, on anion binding. Results indicate a number of corollaries with transition-metal coordination chemistry in terms of binding concepts and geometries for anion complexes.

Author: Bowman-James, Kristin
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2005
Hydrogen bonding, Hydrogen bonds, Coordination compounds, Anions

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Organocatalytic asymmetric epoxidation of olefins by chiral ketones

Article Abstract:

Chiral ketones are shown to be effective organocatalysts for asymmetric epoxidation of olefins with broad substrate scope. The stereochemical outcome of the reaction can be rationalized by a spiro transition state model.

Author: Yian Shi
Publisher: American Chemical Society
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
Olefins, Alkenes, Ketones, Chemical properties

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Subjects list: Research, Chemical reactions
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