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Ultrafast reaction dynamics in molecular cluster ions

Article Abstract:

Researchers are using new techniques to study the influence of a solvent on a molecular scale in reactions in small gas-phase clusters. Experiments on the effect of a solvent on the photodissociation of molecular cluster ions are described.

Author: Faeder, James, Parson, Robert
Publisher: American Association for the Advancement of Science
Publication Name: Science
Subject: Science and technology
ISSN: 0036-8075
Year: 1997
Chemical reactions, Molecular association, Solution (Chemistry), Solutions (Chemistry)

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Germanyl and silyl cations: free at last

Article Abstract:

Akira Sekiguchi et al have successfully synthesized free germanyl and silyl cations for the first time. Their methods and the difficulties of isolation stable cations for germanium and silicon are described.

Author: Schleyer, Paul von Rague
Publisher: American Association for the Advancement of Science
Publication Name: Science
Subject: Science and technology
ISSN: 0036-8075
Year: 1997
Cations, Silicon compounds, Germanium

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