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Zoology and wildlife conservation

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Abstracts » Zoology and wildlife conservation

Reaction discovery enabled by DNA-templated synthesis and in vitro selection

Article Abstract:

A reaction discovery approach that uses DNA-templated organic synthesis and in vitro selection to simultaneously evaluate many combinations of different substrates for bond-forming reactions in a single solution is reported. An efficient and mild carbon-carbon bond-forming reaction is discovered by using this approach that generates an enone from an alkyne and alkene using an inorganic palladium catalyst.

Author: Kanan, Matthew W., Rozenman, Mary M., Sakurai, Kaori, Snyder, Thomas M., Liu, David R.
Publisher: Macmillan Publishing Ltd.
Publication Name: Nature
Subject: Zoology and wildlife conservation
ISSN: 0028-0836
Year: 2004
Usage, DNA microarrays

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Sacrificial synthesis

Article Abstract:

An innovative approach for preparing much sought-after polymer molecule chains with just one chemical group attached at the end with excellent control over the chain length is described. Such structures are of interest in molecular engineering because they are potential building blocks for nanocomposite materials or for biological-synthetic macromolecules.

Author: Perrier, Sebastien, Xiaosong Wang
Publisher: Macmillan Publishing Ltd.
Publication Name: Nature
Subject: Zoology and wildlife conservation
ISSN: 0028-0836
Year: 2007
Polymers, Structure, Atomic properties

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Brevity for bonds

Article Abstract:

Three basic approaches to squeezing carbon-carbon (C-C) bonds, namely caging, crowding and clamping are proposed and examined. In the end, investigating the concept of relative molecular compressibility teaches more about the behavior of molecules than about the size of the deviation from the normal bond length of 1.53 A.

Author: Siegel, Jay S.
Publisher: Macmillan Publishing Ltd.
Publication Name: Nature
Subject: Zoology and wildlife conservation
ISSN: 0028-0836
Year: 2006
Carbon

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Subjects list: Research, United States, Chemical bonds, Chemical properties
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