Molecular chemisorptions of oxygen on Cu6 cluster anions
Article Abstract:
A study is conducted to demonstrate that O2 molecularly adsorbs on Cu6(super -1) at room temperature by using vibrationally resolved ultraviolet photoelectron spectroscopy. By changing the sizes of nanoclusters atom, new chemical properties are observed, which are not expected on the basis of the results from atom, diatomic molecule and respective bulk materials consisting of the same element.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
Effects of TiO2 surface fluorination on photocatalytic reactions and photoelectrochemical behaviors
Article Abstract:
The effects of surface fluorides on TiO2 on both photocatalytic reactions of four organic compounds whose degradation mechanisms are quite different from one another and the photocurrent generation behaviors. As a result, both photoreductive reaction rate and photocurrent generation are reduced on F-TiO2.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
Selective oxidation of the TiC (001) surface by O2: determined by the surface states
Article Abstract:
The oxidation of the TiC(001) surface by O2 has been investigated by using density functional theory with a slab model. A method based on the decomposition of the energy band is presented to describe the band structure of TiC (001) surface on exposure to O2.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Intramolecular excitonic dimers in protease substrates: modification of the backbone moiety to probe the H-dimer structure
- Abstracts: Orientation of 1- and 2-methylimidazole on silver electrodes determined with surface-enhanced Raman scattering
- Abstracts: Modeling of macromolecular alignment in nematic virus suspensions. Application to the prediction of NMR residual dipolar couplings
- Abstracts: Phase transformations in aqueous low molar mass poly(vinyl methyl ether) solutions: Theoretical prediction and experimental validation of the peculiar solvent melting line, bimodal LCST, and (adjacent) UCST miscibility gaps
- Abstracts: Effect of intermolecular hydrogen bonding on low-surface-energy material of poly(vinylphenol). Observation of Quantum paraelectricity in an intermolecular ionic hydrogen-bonded crystal of a squaric acid derivative