An organometallic guide to the chemistry of hydrocarbon moieties on transition metal surfaces
Article Abstract:
The structure and reactivity of varying kinds of hydrocarbon moieties are observed in organometallic compounds and transition metal surfaces. The steps such as C-H and C-C bond breaking and bond forming reactions, isomerization and bonding are discussed. The similarities in the chemical behavior between hydrocarbons in organometallic complexes and in solid metal surfaces is due to the localized nature of chemical bond. Changes in surface coverage affects the rate of molecular reactions, induce adsorbate-adsorbate interaction, and alter the electronic surface characteristics.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1995
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Pulsed gradient spin-echo (PGSE) diffusion and (super 1)H, (super 19)F heteronuclear overhauser spectroscopy (HOESY) NMR methods in inorganic and organometallic chemistry: Something old and something new
Article Abstract:
Pulsed gradient spin-echo (PGSE) NMR diffusion methods were introduced by Stejskal and Tanner and represent a possible supplement to mass spectroscopy. The diffusion data from PGSE measurements provide a unique, relatively rapid way of recognizing and evaluating the general problem of ion pairing.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2005
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