Hemiporphyrazines as targets for the preparation of molecular materials: synthesis and physical properties
Article Abstract:
Hemiporphyrazines are four-unit macrocycles which contain two opposite-faced units and two other hetero-aromatic moeities which are bound through aza bridges. These compounds are considered building blocks of molecular materials. Because of their high synthetic versatility, the compounds' physical properties such as electrical and optical can be easily analyzed. The compounds can also be utilized in the preparation of two-dimensional metal with potential electrical and magnetic properties.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1998
User Contributions:
Comment about this article or add new information about this topic:
Phthalocyanines-versatile components of molecular conductors
Article Abstract:
Pc based conductors with clearly defined structures are described. It is revealed that Pc based conductors had rather unique properties as a 1D system. It is found that the electronic properties at low temperature were severely affected by the defects or impurities in the crystal due to their highly one-dimensional electronic structure.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds
Article Abstract:
Major advances are made in the design and synthesis of phathalocyanines and related materials for nonlinear optical (NLO). The results obtained on the correlation between molecular structure and NLO response is summarized and some strategies for rendering new systems with improved NLO properties are provided.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Charge carrier transporting molecular materials and their applications in devices. Development of dendrimers: Macromolecules for use in organic light-emitting diodes and solar cells
- Abstracts: Dithiadiazafulvalenes: Promising precursors of molecular materials. Synthesis of thiiranes by direct sulfur transfer: the challenge of developing effective sulfur donors and metal catalysts
- Abstracts: In the arena of enantioselective synthesis, titanium complexes wear the laurel wreath. Highly functionalized tetrathiafulvalenes: Riding along the synthetic trail from electrophilic alkynes
- Abstracts: Thiacalixarenes. Polar acetalization and transacetalization in the gas phase: The Eberlin reaction. Allosteric supramolecular receptors and catalysts