Reagent-controlled transition-metal-catalyzed radical reactions
Article Abstract:
This review delineates the laws and principles governing radical chemistry and how reagent control is exercised on these reactions. Metal-catalyzed radical reactions using suitable radical precursors generated by the reagent-controlled reactions aid in the transformation of the radical by the addition of carbon-carbon multiple bonds.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
Ligand bite angle effects in metal-catalyzed C-C bond formation
Article Abstract:
This review discusses the rate and selectivity of metal-catalyzed reactions as influenced by the bite angle of the bidentate ligands. Data reveal that ligands are involved in the stabilization or destabilization of the reaction intermediates and the bite angle brings about the steric hindrance between the ligand and the substrate.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
Synthesis and reactivity of sp(sup)2 geminated organobismetallic derivatives
Article Abstract:
New approaches in organic synthesis have led to minimizing the number of steps involved for achieving efficiency in the synthesis. This review examines such an approach to the synthesis of geminated sp(sup)2 bismetallic derivatives in a single-pot operation and discusses the challenges.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis. Non-metathesis rhenium-catalyzed C-C bond formation
- Abstracts: General aspects of tin-free antifouling paints. Transition-metal-catalyzed reactions in steroid synthesis. Palladium-catalyzed alkynylation
- Abstracts: Selective preparation of complex polycyclic molecules from acyclic precursors via radical mediated- or transition metal-catalyzed cascade reactions
- Abstracts: Methodologies for generating solution-phase combinatorial libraries. Coenzyme A analogues and derivatives: synthesis and applications as mechanistic probes of coenzyme A ester-utilizing enzymes
- Abstracts: Bonding and organic and inorganic reactivity of metal-coordinated phosphinoenolates and related functional phosphine-derived anions