The use of sulfonyl 1,3-dienes in organic synthesis

Article Abstract:

Sulfonyl 1,3-diene is a versatile sulfone-containing synthon. It is used as a starting material in cycloaddition reactions and converted into versatile synthetic intermediates. Moreover, it can generate allylic sulfones when added with a Michael-type conjugate. A review of the use of sulfonyl 1,3-dienes in organic synthesis is presented. This study focuses on 1-sulfonyl 1,3-dienes; 2-sulfonyl 1,3-dienes; 1,3-bis(arylsulfonyl) 1,3-dienes; 1,4-bis(arylsulfonyl) 1,3-dienes; and 2,3-bis(arylsulfonyl) 1,3-dienes.

Analysis, Organic compounds, Organic compound synthesis, Sulfones

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Acylvinyl and vinylogous synthons

Article Abstract:

Research emphasizing the extensive nature of the search for methodologies capable of transferring the significant acylvinyl and vinylogous moieties is presented. Particular attention was given to alpha- and beta-acylvinyl anionic synthons.

Vinyl polymers

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Metalated heterocycles and their applications in synthetic organic chemistry

Article Abstract:

The heterocyclic systems applicable to organic synthesis where the presence of a carbon-metal bond can be found are reviewed. The study shows that impressive amount of synthetic uses that have been found for metalated heterocycles.

Science & research, Carbon, Chemical bonds, Chemical synthesis, Chemical properties

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