Vibrational spectroscopic studies of aqueous interfaces: Salts, acids, bases, and nanodrops

Article Abstract:

Study is conducted to focus on spectroscopic studies of surface water structure as it is affected by salts, acids, and ammonia is focused and cluster studies contributing to understand the aqueous interface along with the studies of aqueous nanodrops. The interfacial structure of water is highly sensitive to the addition of ionic inorganic solutes and the cluster and aqueous nanodrop studies have significantly contributed to unraveling the effect of ions on the surface.

Spectra, Acids, Vibrational spectra, Bases (Chemistry)

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First-principles approaches to the structure and reactivity of atmospherically relevant aqueous interfaces

Article Abstract:

Static and dynamic first-principles method that provides a direct link to the heterogeneous chemistry that takes place in the troposphere and stratosphere is reviewed. Complementary approaches to the modeling of interfacial systems and the state-of-the-art first-principles simulation protocol for ensuring accurate results for the complicated interfacial systems are discussed.

Nitric Acid, Nitrogenous Fertilizer Manufacturing, Nitrogenous fertilizers, Atmospheric chemistry

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Diazonium salts as substrates in palladium-catalyzed cross-coupling reactions

Article Abstract:

A study shows that arenediazonium salts are attractive partners in palladium-catalyzed cross-coupling reactions. The use of arenediazonium salts in palladium-catalyzed reactions has made it possible to synthesize cross-coupled compounds that were not available by using classical halides or oxygen-based electrophiles.

Diazo compounds, Palladium catalysts, Structure, Report

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