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Chemicals, plastics and rubber industries

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AFM observation of immobilized self-oscillating polymer

Article Abstract:

A new nanocomponent is developed that has the function of self-oscillation and a thermoresponsive polymer carrying a Ru complex, a catalyst of the Belousov-Zhabotinsky, is synthesized and immobilized on a glass plate. Periodic turbidity changes in the aqueous solution of the polymer and nanoscale self-oscillation of the immobilized polymer are observed by using atomic force microscopy (AFM).

Author: Onishi, Hiroshi, Uetsuka, Hiroshi, Arakawa, Hideo, Ikai, Atsushi, Hara, Yusuke, Yoshida, Ryo, Ito, Yoshihiro, Hasuda, Hirozazu
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Ruthenium, Usage, Thermal properties, Atomic force microscopy, Structure

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Self-oscillation of polymer chains induced by the Belousov-Zhabotinsky reaction under acid-free conditions

Article Abstract:

The effect of polymer concentration and temperature on the self-oscillating behavior is investigated. The introduction of pH-control site causes the soluble-insoluble self-oscillation of the polymer solution under acid-free conditions in which only two Belousov-Zhabotinsky (BZ) substrates, malonic acid and sodium bromate, is present as added agents.

Author: Hara, Yusuke, Yoshida, Ryo
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
All Other Basic Inorganic Chemical Manufacturing, Potassium & Sodium Compounds, Sodium & Sodium Compounds, Sodium compounds

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Self-Oscillating soluble-insoluble changes of a polymer chain including an oxidizing agent induced by the Belousov-Zhabotinsky reaction

Article Abstract:

The Belousov-Zhabotinsky reaction was utilized for preparing a new type of self-oscillating polymer in which soluble-insoluble self-oscillation of the polymer was first achieved without adding an oxidizing agent. An attempt is made to introduce the oxidizing agent to investigate the effect of temperature on the self -oscillation of polymer chains.

Author: Hashimoto, Shuji, Hara, Yusuke, Yoshida, Ryo, Sakai, Takamasa, Maeda, Shingo
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Oxidizing agents, Oscillation, Oscillations

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Subjects list: Analysis, Chemical properties, Belousov-Zhabotinskii reaction, Polymers
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