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Chemicals, plastics and rubber industries

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FTIR spectroscopic and reaction kinetics study of the interaction of CF3CfCl2 with gamma-Al2O3

Article Abstract:

An investigation into the interaction of CF3CfCl2 with gamma-Al2O3 uses a combination of FTIR spectroscopic research and reaction kinetics experiments. Details of the study are discussed.

Author: Deshmukh, Subodh S., Kovalchuk, Vladimir I., Borovkov, Victor Yu., d'Itri, Julie L.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Metal halides, Metallic oxides, Metal oxides

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Fourier transform infrared study of 1,1-dichlorotetrafluoroethane adsorption on an alumina-supported Pd catalyst

Article Abstract:

Research into CF3CFCl2 adsorption on 5% Pd/gamma-Al2O3 at room temperature is presented. It was established that three types of surface species form.

Author: Kovalchuk, Vladimir I., Borovkov, Victor Yu., d'Itri, Julie L., Lonyi, Ferenc
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Catalysts, Adsorption, Surface chemistry

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Hydrogen-assisted 1,2-dichloroethane dechlorination catalyzed by Pt-Cu/SiO2: Evidence for different functions of Pt and Cu sites

Article Abstract:

A study is conducted to examine a monometallic PT/SiO(sub 2) and two bimetalic Pt-Cu/SiO(sub 2) atomic ratio of 1 (Pt1Cu1) and 0.33 (Pt1Cu3) by a combination of reaction kinetics and FTIR spectroscopic studies. The addition of CO into the CH(sub 2)Cl-CH(sub 2)Cl+H(sub 2) reaction mixture at 473 K to0 block Pt sites resulted in a significant improvement in the ethylene selectivity of the bimetallic catalysts at the expense of ethane.

Author: Borovkov, Victor Yu., d'Itri, Julie L., Luebke, David R, Kovalchuk, Vladimir I
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Platinum, Copper, Chemical properties

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Subjects list: Research, Chemistry, Physical and theoretical, Physical chemistry, Chemical reactions
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