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Chemicals, plastics and rubber industries

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Identification of CO absorbed at Ru and Pt sites on a polycrystalline Pt/Ru electrode and the observation of their oxidation and free interchange under open circuit conditions

Article Abstract:

The spontaneous oxidation of CO adsorbates on a Pt electrode modified by Ru under open circuit (OC) conditions in perchloric acid solution is followed, for the first time, using in situ FTIR spectroscopy, and the dynamics of the surface processes taking place are elucidated. The IR data show that adsorbed CO present on both the Ru and Pt domains and can be oxidized by the oxygen-containing adlayer on the Ru in a chemical process.

Author: Christensen, Paul A., Jia-Mei Jin, Wen-Feng Lin, Hamnett, Andrew
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Platinum, Usage, Fourier transform infrared spectroscopy

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Carbon monoxide dissociation on planar and stepped Ru(0001) surfaces

Article Abstract:

The calculations on the geometries and energy barriers for carbon monoxide decomposition on flat ruthenium surfaces through an indirect route are given. The procedures used in the study are explained.

Author: Santen, R.A. van, Ciobica, I.M., Ying-Cai Long, Dyer, Daniel J., Wang, Lichang
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, Research, Dissociation, Dissociation reactions, Atomic properties

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Subjects list: Carbon monoxide, Chemical properties, Ruthenium
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