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Reply to the comment on "two dimensional NMR study on the structures of micelles of sodium taurocholate"

Article Abstract:

The dimer and micelle of sodium taurocholate (TC) have the back-to-back structure as revealed by two-dimensional NMR spectroscopy. The dimer and micelles of TC in aqueous media have the back-to-back structure association (normal micelle) driven by hydrophobic interaction instead of those of face-to-face association (reverse micelle) driven by ionic interaction of hydrogen bonds.

Author: Funasaki, Noriaki, Nomura, Masao, Ishikawa, Seiji, Neya, Saburo, Fukuba, Makoto, Kitagawa, Tomohiro, Hirota, Shun
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Analysis, Nuclear magnetic resonance spectroscopy, Hydrogen bonds

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Hydrophobic self-association of sodium taurochenodeoxycholate and tauroursodeoxycholate

Article Abstract:

The aggregation patterns of sodium taurochenodeoxycholate and tauroursodeoxycholate (TUDC) in an isotonic sodium chloride solution are investigated. The result suggests that 7beta-hydroxyl group of TUDC inhibits micellar growth because of increased intermolecular mismatching contact with the hydrophobic surface and decreased intermolecular hydrogen bonds in the micelle.

Author: Funasaki, Noriaki, Nomura, Masao, Ishikawa, Seiji, Neya, Saburo
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Hydroxides, Hydrophobic effect

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Two-dimensional NMR study on the structures of micelles of sodium taurocholate

Article Abstract:

The micellar structure of sodium taurocolate (TC) in the deutrium oxide on the basis of two-dimensional NOE spectroscopy is presented. It is concluded that the concentration dependence of the chemical shift of TC is explicable in terms of dimerizatin and pentamierization.

Author: Funasaki, Noriaki, Nomura, Masao, Ishikawa, Seiji, Neya, Saburo, Fukuba, Makoto, Kitagawa, Tomohiro, Hirota, Shun
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Industrial inorganic chemicals, not elsewhere classified, Heavy Water, Usage, Nuclear magnetic resonance, Structure

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Subjects list: Hydrogen bonding, Sodium compounds, Chemical properties, Research
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