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Homogenous-phase electron-transfer reactions of polyoxometalates

Article Abstract:

A comprehensive analysis of published data regarding the mechanisms of homogeneous-phase electron-transfer reactions between polyoxometalate anions and organic or inorganic electron donors or acceptors is presented. The theoretical models of Marcus, Sutin and others are used for the observation of the homogeneous-phase outer-sphere electron-transfer processes and for the comparison of experimentally determined rate constants.

Author: Weinstock, I.A.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1998
Analysis, Oxidation-reduction reaction, Oxidation-reduction reactions

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Structure and reactivity of early-late heterobimetallic complexes

Article Abstract:

A review of work on the structure and reactivity of early-late heterobimetallic complexes published between January 1988 and December 1997 is presented.

Author: Wheatley, Nigel, Kalck, Philippe
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 1999

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Subjects list: Research, Coordination compounds
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