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Synthetic analogues of cysteinate-ligated non-heme iron and non-corrinoid cobalt enzymes

Article Abstract:

The progresses that are made in an attempt to determine the roles played by cysteinate sulfur ligands in promoting non-heme iron enzyme functions are presented. The molecular details regarding metalloproteins function are revealed.

Author: Kovacs, Julie A.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Metalloproteins

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Synthetic analogues of the active sites of iron-sulfur proteins

Article Abstract:

The synthetic analogue approach to the metal sites in iron-sulfur proteins is discussed in detail. The way in which inorganic chemistry and biochemistry can be brought together in a synergistic manner is presented.

Author: Rao, P.Venkateswara, Holm, R.H.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Proteins

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The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters

Article Abstract:

The synthetic methods, structures, and selected properties of clusters are highlighted. However, the synthetic challenge posed by the nitrogenase metaloclusters with their intrinsic property remains formidable.

Author: Holm, R.H., Lee, Sonny C.
Publisher: American Chemical Society
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
Analysis, Nitrogenase, Chemical synthesis, Structure

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Subjects list: Sulfur, Iron compounds, Chemical properties, Sulphur
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