Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles

Article Abstract:

This article discusses the use of palladium catalysts for the alpha-arylation of carbonyl compounds such as ketones and the mechanism involved in the product-forming reductive elimination step. Research describes the structures and reactions of arylpalladium complexes to understand the binding mode and electronic and steric factors that influence the rate and mechanism of reductive elimination.

Chemical reactions, Mechanical chemistry, Palladium catalysts, Mechanochemistry

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Lanthanide-transition-metal complexes: from lon Paris to extended arrays

Article Abstract:

The work on lanthanide-transition-metal (Ln-M) systems is outlined. The development of synthetic methodology for novel Ln-M compounds and the investigation for their structures is the theme of the research.

All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Rare Earth Compounds, Molecular structure, Rare earth metal compounds

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Structural and mechanistic insights into methane oxidation by particulate methane monooxygenase

Article Abstract:

A structural biochemical and spectroscopic investigation into the oxidation of methane to methanol by particulate methane monooxygenase (pMMO) is discussed.

Methane, Oxidases

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